Product ID:AEROSOL PROPELLANT REFILL, A1147
MSDS Date:12/07/1988
FSC:6810
NIIN:00N022060
MSDS Number: BMNSN

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 800-325-8070; 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

METHANE, DICHLORODIFLUORO-; (DICHLORODIFLUOROMETHANE)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: >70%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPANE, 2-METHYL-; (ISOBUTANE)

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: >70%

METHANE, TRICHLOROFLUORO-; (TRICHLOROFLUOROMETHANE)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 1-10%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(ACUTE) LIGHT HEADEDNESS, GIDDINESS,
SHORTNESS OF BREATH, POSSIBLE NARCOSIS, POSSIBLE CARDIAC
ARRHYTHMIAS AT HIGH CONC. MAY CAUSE FROSTBITE ON DIRECT CONTACT.
MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. USE
ONLY AS DIRECTED. INTENTIONAL MISUSE BY DELIBERATELY CONC VAPORS &
INHALING(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CONTENTS CAN BE HARMFUL/FATAL.
CHLOROFLUOROCARBON (CFC) MATLS HAVE PRODUCED SENSIT OF THE
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT
IN HUMANS. ADRENOMIMETICS (E.G. EPI NEPHRINE) MAY BE
CONTRAINDICATED EXCEPTFOR LIFE- SUSTAINING USES IN HUMANS
ACUTELY/CHRON EXPSD TO CFC'S .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS
CONSCIOUS.CALL MD.SKIN:FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST
15 MIN.REMOVE CONTAM CLTHG & SHOES & CALL MD.INHAL:REMOVE TO FRESH
AIR.IF BRTHG BECOM ES DFCLT, CALL MD.EYES:FLUSH W/COPIOUS AMTS OF
WATER FOR AT LEAST 15 MIN.ASSURE ADEQ FLUSH BY SEPARATING LIDS
W/FINGERS.CALL MD.NOTE TO MD:IN CASES OF OVEREXP DO NOT GIVE
EPINEPHRINE/SIMILAR DRUGS.

Flash Point:NON-COMBUSTIBLE
Extinguishing Media:NON-COMBUSTIBLE. USE EXTINGUISHING MEDIA
APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:COMPRESSED GAS. THERMAL DECOMPOSITION
PRODUCTS MAY INCLUDE HCL, FLUORIDES & PHOSGENE .

Spill Release Procedures:VENTILATE AREA - ESPECIALLY LOW PLACES WHERE
HEAVY VAPORS MIGHT COLLECT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE AWAY FROM HEAT, SPARKS, AND OPEN
FLAME. HEAT-SENSITIVE. WARNING: CONTAINS CHLOROFLUOROCARBONS THAT
MAY HARM THE ENVIRONMENT.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL, FLUORIDES AND/OR
PHOSGENE .

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:G3
Vapor Pres:62(+-)3
Vapor Density:>1
Evaporation Rate & Reference:<1
Solubility in Water:WATER-INSOLUBLE
Appearance and Odor:LIQUID WITH NO ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:KEEP AWAY FROM HEAT AND OPEN FLAME.
Hazardous Decomposition Products:TOXIC FUMES OF: HALIDES, ACIDS,
PHOSGENE GAS. HCL, FLUORIDES & PHOSGENE .

Waste Disposal Methods:AEROSOL CONTAINER: DO NOT PUNCTURE OR INCINERATE
CAN. WHEN ALL LIQUID IS EXPELLED, CONTINUE TO DEPRESS BUTTON UNTIL
ALL GAS IS EXPELLED. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.